botty wrote: ...The chain is cleaned weekly, not by removing but with a thorough clean in situ with transmission degreaser and a toothbrush. Then it has a proper lubrication with bicycle chain lube, just finished off a bottle of green line wet.
Do you mean finish line wet?
It might be that your chain cleaning/lubing routine can be improved; but there is no one 'right way' here.
Another possibility is that the chain was substandard in some way; occasional QA problems are not unknown in any factory. IIRC Wipperman made a whole load of quicklinks that broke a few years ago, so they have 'previous form' on the QA front. You could have excessive roller wear (rather than bushing wear) so I'd suggest you check the elongation of the chain with a ruler over a 12" length.
But having said that, chains usually wear because their factory-applied coatings (not all chains) are stripped/worn off, and the lubricant fails in some way. Lube can fail in several ways;
1) lube gets dirty. Wet lubes are pretty good at this. If you are going to clean the chain, clean it fully.
2) lube is otherwise contaminated. Degreaser residue (doesn't evaporate in cold conditions), road salt, water etc degrades the lube.
3) lube fails to protect against corrosion. Bushings etc wear via corrosion/erosion once the lube film is breached in the bushing. In addition the chain can corrode internally when the bike is not is use; salt water is the usual culprit.
You can tell if the chain is corroding internally. If you pull the bike out of the shed and spray the chain with water-displacing lube (GT85 or WD40) and run it round for a few turns, you may see brown rust-coloured stuff oozing out of the chain.
If you do the same thing with a 'clean' chain and there is any sign of blackness when you wipe the chain off, the chain isn't really clean. The black stuff is a mixture of wear debris and dirt; IME removing it all greatly decreases the wear rate of any chain, even if it is but a temporary state of affairs.
I have to own up to not being a fan of some wet lubes, even those from companies where (say) I love their grease etc. These lubes are ridiculously priced; if you pay £4 for 120ml for 'oil plus some additives' then (say) at that rate a 5l can of motor oil would cost about £160 quid. If you have an expensive wet lube the temptation is to use it sparingly; this means that the lube is more likely to become a grinding paste. Although some wet lubes seem to leave a gungy layer over the outside of the chain, they don't always inhibit salt water corrosion inside where it matters.
But the bottom line is that if you chain is truly worn out in 400 miles, this is an exceptional state of affairs. Even a dirty chain (with lots of oil on it) would last 400 miles without clapping out, so my vote is for a duff chain or a chain that has suffered internal wear/corrosion through ingress of salty water or something.
[BTW dirt on the outside of the chain does matter; it also accelerates the wear on the sprockets and chainrings. Arguably a stretched chain is worse, because it will wear the other parts such that they won't take a new chain any more, but dirty chains cause wear, no mistake. ]
cheers